Parametric Representation of the Equation of State Near A Critical Point

P. Schofield
Phys. Rev. Lett. 22, 606 – Published 24 March 1969
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Abstract

A parametric representation of the usual thermodynamic variables in the neighborhood of a critical point is proposed in terms of new variables r and θ. The representation is chosen so that the "scaling-law" behavior is entirely contained in the r dependence, the θ dependence being free of critical singularities. Preliminary calculations show that the θ dependence may be chosen to have a rather simple form both in a ferromagnet and in fluids.

  • Received 2 January 1969

DOI:https://doi.org/10.1103/PhysRevLett.22.606

©1969 American Physical Society

Authors & Affiliations

P. Schofield*

  • Department of Physics and Center for Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts

  • *Permanent address: Theoretical Physics Division, Atomic Energy Research Establishment, Harwell, England.

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Issue

Vol. 22, Iss. 12 — 24 March 1969

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